Microelectronic device drying devices and techniques

ABSTRACT

Improved methods of rinsing and drying microelectronic devices by way of an immersion processing apparatus are provided for effectively cleaning microelectronic devices. Methods and arrangements control the separation of one or more microelectronic devices from a liquid environment as part of a replacement of the liquid environment with a gas environment. Cleaning enhancement substance, such as IPA, is introduced into the gas environment according to a controlled profile while the separation step is conducted. The controlled profile being directed to the timing of introduction of cleaning enhancement substance, the concentration of cleaning enhancement substance and/or flow rates thereof into the vessel. Controlled timing of gas and cleaning enhancement substance delivery can also improve effectiveness of separation. Methods and arrangements are also provided for controlling a drying step to be conducted on the one or more microelectronic devices after they have been separated from a liquid environment by replacing the liquid environment with a gas environment. Preferably, an arrangement of gas distribution devices create one or more drying gas curtains, which gas curtains may be controllably directed with respect to a set of microelectronic devices to provide optimal drying of the microelectronic devices after being separating from a liquid.

CROSS REFERENCE TO RELATED APPLICATION

This application is a divisional application of U.S. application Ser.No. 10/608,894, filed Jun. 27, 2003, entitled “MICROELECTRONIC DEVICEDRYING DEVICES AND TECHNIQUES” now allowed, the entire disclosure ofwhich is incorporated herein by reference.

FIELD OF THE INVENTION

The present invention relates to immersion or wet processing andcleaning of microelectronic devices, such as semiconductormicroelectronic devices, and to enhanced techniques and methods foroptimizing the rinsing and cleaning aspects of such devices. Inparticular, the present invention is directed to improving an aspect ofsuch rinsing and cleaning operation wherein such microelectronic devicesare cleanly separated from a liquid bath.

BACKGROUND OF THE PRESENT INVENTION

At some point during any immersion or wet processing operation, theobject being processed is separated from its liquid bath. This may occurmany times depending on such process and device at intermediate or finalstages of processing. Such may occur in one or more immersion vessels assequential steps or separated by other different process steps. As ageneral matter, and depending of the process, it may be desirable torinse an object for cleaning it after being subjected to processingfluid in order to remove any contaminants or residual processing fluid.Moreover, the object may be further dried to remove any processing orrinsing liquids and to provide a clean processed object.

In the case of processing microelectronic devices, such as thoseincluding semiconductor wafers and microelectronic devices at any ofvarious stages of processing, flat panel displays,micro-electrical-mechanical-systems (MEMS), advanced electricalinterconnect systems, optical components and devices, components of massdata storage devices (disk drives), and the like, cleanliness iscritical in virtually all processing aspects. Representative steps inimmersion processing of microelectronic devices include microelectronicdevice etching and rinsing. As used herein, immersion processing means aprocess where at least a portion of a device, such as a microelectronicdevice, is subjected to immersion for a period of time for any effectivepurpose.

One important aspect in providing clean microelectronic devices afterimmersion processing is to start with the use of clean processingliquids. Clean liquid use can be controlled by known or developedfiltering processes so as to minimize introduction of contaminants intothe processing environment. This is particularly true where devices arebeing cleaned or rinsed by an immersion process, such as by usingdeionized water (DI water) as a rinsing liquid as either flowing ornon-flowing liquid bath. Specific filtering techniques for ultra-cleanDI water have been developed for use in the microelectronic industry,such as those described in U.S. Pat. Nos. 5,542,441, 5,651,379 and6,312,597 to Mohindra et al. Microelectronic devices are often rinsedwithin vessels as a batch or individually by flowing DI water acrossdevice surfaces as supported within the vessel and cascading the DIwater from the vessel. Such a process vessel for microelectronic devicerinsing is commonly referred to as a cascade rinser. Cascade rinsingtypically utilizes an immersion vessel having inner and outer chambersthat are separated from one another by a partition or weir. One or moredevices are positioned within the inner chamber of the immersion vessel.Rinse liquid, such as DI water, is supplied to the inner chamber from asource even after the inner chamber is filled. For some desired periodof time then, the rinse liquid overflows and cascades over the weir intothe outer chamber. That way contaminants that may be dislodged and/orresidual process fluid desirably flow with the cascaded liquid from theinner chamber and away from the devices.

It is also just as important to prevent contamination or recontaminationto a surface of a microelectronic device, as such contaminant may bepresent in the processing liquid as a result of being supplied withinthe process liquid, as previously dislodged from a device surface, or asa result of the device processing (including previously used processingliquids or other liquid contaminants). This is particularly true whenseparating the microelectronic device(s) from the liquid bath so that nosubstantial surface contamination occurs from contaminants that may besuspended within the rinse or other processing liquid. Microelectronicdevices may be separated from any liquid bath by lifting the devicesfrom the bath or draining the liquid bath, or a combination of the two.During such separation, contaminants that may be near a device surfaceduring separation can sometimes be deposited onto a device surfacedepending on surface and particle features, affinities and sizes.

Regardless of the mechanisms involved, the basic step of separation maysimply be characterized as the controlled replacement of a liquidenvironment about an object or portion thereof with a gas environment.As a result, the object or portion thereof is separated from the liquid.In an inline process, separation is typically done by replacing onefluid that is supplied inline with a subsequent fluid (e.g., changingfrom rinse liquid to clean gas). See, for example, U.S. Pat. Nos.4,984,597 and 4,911,761 to McConnell et al. For a liquid bath typeimmersion process (i.e., where one or more microelectronic devices aresupported or suspended within liquid contained by a vessel), the liquidenvironment can be controllably replaced with a gas environment bylifting or draining, as above.

In order to enhance this separation step, processes have been developedthat introduce a substance within the gas environment during thereplacement stage about an object that causes the liquid to shed moreeasily from the object surfaces. By shedding the liquid better, there isless a likelihood that any contaminant would be deposited onto an objectsurface from the liquid, and there is an increased chance to remove anysuch contaminant from an object surface. Developed processes utilizeisopropyl-alcohol (IPA), in particular, to take advantage of what isknown as the Marongoni effect to create a gradient in the concentrationof the IPA mixed with the liquid at or near the liquid/gas meniscusformed at the object surfaces. The concentration gradient causes anacceleration of the liquid from an object surface as liquid having agreater concentration of the IPA within such a meniscus has an increasedtendency to flow toward a more dilute mixture of IPA within the liquidbath. Many processes and systems have been developed taking advantage tovarious degrees such Marongoni effect to enhance rinsing and cleaning ofmicroelectronic devices.

In particular, certain apparatuses and methods have been developed asare described with U.S. Pat. No. 5,772,784 to Mohindra et al, and whichis owned by the assignee of the present invention. Described processessteps include the introduction of IPA as a cleaning enhance substancewithin a carrier gas stream for delivering a dilute concentration of IPAwithin the gas environment as it replaces the liquid environment causedby draining the immersion vessel. The IPA is relied upon, as describedabove, to increase the tendency of the liquid to flow from objectsurfaces during the step of separating the object(s) from the liquid.

Whereas the main goal of separation is to leave clean device surfaces,the separation step itself, however, does not necessarily result in drydevices. That is, after a rinsing step, a separate drying step may beperformed to dry liquid drops or films that may still be present. Aparticular drying operation utilized depends on parameters of theseparation (e.g. speed of separation, orientation of the microelectronicdevices, and the like) as well as characteristics of the microelectronicdevices themselves (e.g. the hydrophilic or hydrophobic nature of thedevice surface). Any liquid droplets or films that remain on amicroelectronic device surface after separation, such as may result ator near contact points with support structure or as minute droplets orfilms that hold to the microelectronic device surface, are desirablyremoved from the microelectronic device surface. If such droplets orfilms are left to evaporate from the microelectronic device surface, anycontaminants within the droplets or films can be deposited on themicroelectronic device surface, which contaminants may render a portionof the microelectronic device unsuitable for further processing or use.Known drying techniques include the use of heated gases, such as heatednitrogen gas, after the rinsing step for removing unwanted droplets andfilms from the microelectronic device surfaces.

SUMMARY OF THE PRESENT INVENTION

The present invention overcomes certain shortcomings of the prior art byimproving the methods of rinsing and drying microelectronic devices byway of an immersion processing apparatus and for effectively cleaningmicroelectronic devices.

In one aspect, the present invention is directed to methods andarrangements for controlling the separation of one or moremicroelectronic devices from a liquid environment and the replacement ofthe liquid environment with a gas environment. In particular, cleaningenhancement substance, such as IPA, is introduced into the gasenvironment according to a controlled profile while the separation stepis conducted. The controlled profile potentially including, according toa desired process, not only when the introduction of cleaningenhancement substance is commenced and ceased, but also theconcentration of cleaning enhancement substance and flow rates thereofinto the vessel.

According to certain preferred methods, flow rates of even or differinggas concentrations of cleaning enhancement substance can be variedaccording to selected stages of separation. In a preferred technique,gas mixture flow rates can be increased or decreased in stages orgradually over time at a fixed or varied slope as the separationprogresses. Where an immersion vessel is drained to cause suchseparation of one or more microelectronic devices from a liquid, theflow rate of gas mixed with cleaning enhancement substance can beincreased as the liquid level becomes lower in the vessel. That way, gasflow can be minimized when the liquid level is high, in particular,where the gas mixture is introduced from above to minimize rippling ofthe liquid surface and any influence of surface flow of the liquid. Flowrates can be increased one or more times as the level lowers to ensuresufficient delivery of cleaning enhancement substance to the liquid topsurface and thus the menisci formed at the one or more devices.Concentration of cleaning enhancement substance can be the same orvaried over time as well.

Controlled timing of gas and cleaning enhancement substance delivery canalso improve effectiveness of separation. By continuing flow of the gasand cleaning enhancement substance even after separation of one or moredevice is complete, liquid drops or film left on any device surface canbe better contained on such surface. Such containment can be effected bysuch continued flow up until, into or throughout a subsequent dryingstep. That way, potential contamination from any contaminant within suchdrop or film can be limited to that specific area where the drop or filmwas contained. This is particularly advantageous where drops are formedwithin exclusion zones, such as a commonly provided with certainmicroelectronic devices or microelectronic devices, and as such aretypically formed at carrier contact points that contact such devices atan edge thereof.

In another aspect, the present invention is directed to methods andarrangements for controlling a drying step to be conducted on the one ormore microelectronic devices after they have been separated from aliquid environment by replacing the liquid environment with a gasenvironment. As noted above, steps or methods of the separating step canbe carried over into a drying step, for example, to contain liquid dropsor films. The drying operation itself is also preferably controlled toenhance drying of all desired surfaces of such microelectronic devices.A preferred method of drying microelectronic devices is to utilize cleangas flow directed across such devices to cause liquid to evaporate orfor the liquid to be blown from the device surface.

Contact points between a carrier or other support or handling structureand the one or more microelectronic devices are where liquid is morelikely to accumulate after a separation step. However, other points mayretain some liquid based upon other characteristics of the operationincluding the speed of separation, orientation of the microelectronicdevices, and the like, as well as characteristics of the microelectronicdevices themselves, such as the hydrophilic or hydrophobic nature of thedevice surface. For example, liquid accumulating at the low point of acircular microelectronic device arranged vertically is a knownpossibility. Liquid accumulation at contact points or low spots can beeven more difficult to dry where many microelectronic devices arearranged in a spaced stack, for example, or anywhere where adjacentsurfaces are relatively close to one another as compared with devicedimensions. Such closely spaced surfaces can be sheltered by othersurfaces to reduce effectiveness of gas flow drying techniques.

Thus, it is also desirable to control a drying operation by effectivelycontrolling gas flow as directed about one or more microelectronicdevices after separation from a liquid environment. Preferable anapparatus is provided including an arrangement of one or more nozzlesthat extend at least partially across an immersion vessel interiorcavity. Preferably, an arrangement of gas distribution devices createone or more drying gas curtains, which gas curtains may be controllablydirected with respect to a set of microelectronic devices to provideoptimal drying of the microelectronic devices after being separatingfrom a liquid. Gas curtains in accordance with the present invention canresult from the arrangement of plural nozzles and/or based upon thespecific nozzle design of each nozzle, such as on the size, spacing andnumber of gas directing orifices. Preferably, the size and number ofnozzles is substantially related to the number and arrangement ofmicroelectronic devices to be processed within the vessel.

Utilizing such controllably directable gas curtains has many benefits. Asimple mechanical design may be used which includes minimal movingparts. Gas distribution devices for providing gas curtains in accordancewith the present invention may be formed from simple structures and maynot require complex gas handling techniques. Moreover, controllablydirected gas curtains can advantageously be utilized to adjust thedrying characteristics a particular immersion processing apparatus andmicroelectronic device size.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic view in cross-section of an immersion apparatus inaccordance with the present invention showing a set of microelectronicdevices supported within an immersion vessel of the immersion apparatus,wherein the microelectronic devices are subject to a gas environment, inparticular for drying;

FIG. 2 is a cross-sectional view of the immersion apparatus of FIG. 1taken along line 2-2 of FIG. 1;

FIG. 3 is a cross-sectional view of the immersion apparatus of FIG. 1taken along the line 3-3 and showing one preferred gas controlarrangement having a nozzle of the present invention for delivering acleaning enhancement substance to the immersion vessel and three gasdistribution devices of the present invention for directing drying gasflow curtains to the set of microelectronic devices positioned withinthe immersion vessel;

FIG. 4 shows a cross-sectional view similar to FIG. 2 additionallyshowing plural controllably directed gas flow curtains in accordancewith one aspect of the present invention, such gas flow curtains beingdirected according to one exemplified flow pattern primarily toward thebottom wall of the immersion vessel by the gas distribution devices;

FIG. 5 shows a cross-sectional view similar to FIG. 4 but instead showsa different exemplified flow pattern for the controllably directed gascurtains that are moreso directed toward the side walls of the immersionvessel by the gas distribution devices;

FIG. 6 is a perspective view of an exemplary gas distribution device ofthe present invention showing in particular plural orifices fordistributing gas therefrom;

FIG. 7 is a partial cross-sectional side view of a gas distributiondevice of the present invention positioned above a plurality ofmicroelectronic devices and showing in particular plural gasdistribution orifices;

FIG. 8 is a schematic view similar to FIG. 1 showing pluralmicroelectronic devices supported with the immersion vessel while themicroelectronic devices are subject to a liquid bath environment;

FIG. 9 is a schematic view similar to FIG. 8 showing the liquidenvironment being replaced with a gas environment and with cleaningenhance substance being introduced into the gas environment; and

FIG. 10 is a schematic view showing fluid flow and control aspects of asystem in accordance with another aspect of the present invention forsupplying cleaning enhancement substance to an immersion vessel.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

With reference to the accompanying Figures, wherein like components arelabeled with like numerals throughout, and initially to FIGS. 1 and 2,an immersion processing apparatus 10 is shown. The apparatus 10 may beused for processing, rinsing, and drying of microelectronic devices,such as semiconductor wafers at any of various stages of processing,flat panel displays, micro-electrical-mechanical-systems (MEMS),advanced electrical interconnect systems, optical components anddevices, components of mass data storage devices (disk drives), or thelike. In accordance with a number of aspects of the present invention,the apparatus 10 provides improved rinsing/cleaning and dryingcapabilities for such microelectronic devices.

The apparatus 10 preferably includes an immersion vessel 12, asschematically illustrated, which is preferably capable of containing anyquantity of processing liquid (not shown) as utilized for affecting orcleaning one or more microelectronic devices. The processing liquid maycomprise any processing liquid to which exposure to at least a portionof such microelectronic device(s), such as microelectronic devicesurfaces, is desired and which processing liquid is to be delivered asan immersion or liquid bath type process and that may be controllablycaused to flow with respect to the microelectronic devices. As oneexample, processing liquid may comprise an active processing fluid suchas an etchant, which could be an HF solution, a buffered HF solution, anHCl solution, or the like. As another example, processing liquid maycomprise a passive processing fluid such a rinsing fluid, which could beDI water or the like. More preferably, processing liquid may compriseultra-purified DI water, such as may be obtained by a filtering systemdescribed in commonly owned U.S. Pat. Nos. 5,542,441, 5,651,379 and6,312,597 to Mohindra et al., the entire disclosures of which areincorporated herein by reference. Thus, in one exemplary process inaccordance with the present invention, microelectronic devices may beetched by a first processing liquid, rinsed by a second processingliquid, and then subsequently dried by a drying gas after beingseparated from the rinsing liquid. Such etching and/or other processingsteps can be conducted within a same or different immersion vessel assystems for moving microelectronic devices between vessels are wellknown.

The apparatus 10 preferably comprises the ability to support one or moremicroelectronic devices within the immersion vessel 12. For, example, aset of microelectronic devices 14 is shown positioned entirely withinthe immersion vessel 12 and supported therein by a microelectronicdevice support device or cassette 16. As shown, the cassette 16 ispreferably positioned and supported within the immersion vessel 12 by asupport structure 15, which may comprise one or more elements providinga support floor spaced above the vessel bottom. Preferably, theapparatus 10 further includes a removable lid 18 to permit selectiveaccess to the inside of vessel 12 and a controlled environment in vessel12 when the lid 18 is closed. Also illustrated is an exemplaryarrangement for providing one or more gas outlet devices. Theillustrated arrangement includes a nozzle 20 for supplying a cleaningenhancement substance and gas for replacing a liquid environment with agas environment, as described below, while a plurality of other gasdistribution devices 22, 24, and 26 are provided for controlled deliveryof a drying gas flow, preferably in the pattern of flow curtains asdescribed below and/or for supplying a cleaning enhancement substance,as also described below. Any one or each of gas distribution devices 22,24 and 26 can be used to provide gas in accordance with all aspects ofthe present invention as described below. Moreover, the devices 22, 24and 26 can be modified in size, shape, and functional gas deliveryaspects based merely upon the ability to deliver gases as describedbelow, although certain design features are preferred for directing gasflow, such as for drying purposes, also described below.

A typical microelectronic device is illustrated throughout the figuresas a wafer having first and second major, generally oppositely facing,surfaces. Microelectronic devices and wafers may comprise semiconductormaterials, such as silicon and gallium arsenide, insulator materials,such as sapphire, quartz, and glass, metallic materials, such as copperfor example, or combinations thereof such as silicon-gallium arsenidehybrid substrates. Microelectronic devices may further includesubstrates for hybrid microelectronics manufacture such those formedfrom ceramics or the like. Certain microelectronic devices, such assemiconductor wafers or other microelectronic devices (or substrates),are preferably processed in sets of twenty-five, fifty, or fifty-twomicroelectronic devices, which are usually delivered to amicroelectronic device processing system together in a transfer device.A set of microelectronic devices may be transferred from any suchtransfer device or provided directly instead to a process carryingdevice, such as a cassette 16, for processing in any of a number ofprocessing systems. Although the principles of the present invention mayadvantageously be applied a set of microelectronic devices, theprinciples of the present invention may by applied to any number ofmicroelectronic devices, including a single microelectronic device.

The cassette 16 may be any cassette or support device capable ofsupporting one or more devices, such as the illustrated set ofmicroelectronic devices 14. For example, microelectronic device edgesupporting systems and methods that may or may not utilize cassettes canbe used alternatively such as is described in co-pending U.S. patentapplication Ser. No. 10/292,807, entitled “Semiconductor Microelectronicdevice Cleaning Systems and Methods,” and filed on Nov. 11, 2002, theentire disclosure of which is incorporated by reference herein, andwhich is commonly owned by the assignee of the present invention.

The cassette 16 can be movable between locations such as by a robot orthe like. Alternatively, the cassette 16 may instead be a supportstructure of the immersion vessel 12 within which microelectronicdevices may be loaded into and out of the cassette 16 by a robot or thelike from another cassette or carrying device. Also, the cassette 16 maybe attached to a lifting device (not shown) for moving the cassette 16in and out of the immersion vessel 12 and may be loaded and unloaded bya robot, for example. A microelectronic device processing system neednot use cassettes at all, but may instead move one or more devicesaround with other handling mechanisms, which mechanisms may includedevice support structure or may place such devices within supportstructure of the process equipment, such as within a vessel of animmersion apparatus.

For the purpose of illustration, a cassette 16 is shown comprising twosubstantially parallel rods 17, each rod 17 having plural spaced notches19 for receiving microelectronic devices 14 to be supported togetherwith a pair of end members 21 positioned at the ends of the rods 17. Theparallel rods 17 can be spaced apart such that substantially planarobjects, such as semiconductor wafers, can fit between the rods 17 andrest in the spaced notches 19 in the rods 17. As such, microelectronicdevices can be held in place by gravity, although other clamps,mechanical devices or the like can also be provided. Typically, a set ofmicroelectronic devices, as supported by the cassette 16, are regularlyarranged along a central axis of the microelectronic devices and areregularly spaced apart from one another so that device major surfacesare substantially parallel to each other.

Preferably, the cassette 16 or other support structure is also designedto accommodate desired fluid flow requirements in accordance with thepresent invention. In particular, the cassette 16 is preferably designedto minimize any fluid build up or accumulation that might occur atcontact points between support structure of the cassette 16 and themicroelectronic devices carried by the cassette 16. For processingeffectiveness, it is preferable that each microelectronic device besufficiently spaced from adjacent microelectronic devices to allow anadequate flow of the various processing and rinsing solutions to providesubstantially uniform surface treatment to relevant surfaces of eachmicroelectronic device. In addition, it is also preferable that themicroelectronic devices be supported close to its outer perimeterthroughout the various processing and rinsing steps in order to providethe processing and rinsing fluids with substantially unobstructed accessto the critical surfaces of each microelectronic device. Currentmicroelectronic device processing guidelines allow for handling withinthe outer 3 mm of each microelectronic device, as such area isconsidered to be the unusable portion of the microelectronic device andis often referred to as the exclusion zone of the microelectronicdevice. To provide additional usable area of each microelectronicdevice, it may be desirable to further limit handling of microelectronicdevices even closer to its edges, such as the outer 1 mm of eachmicroelectronic device, for example.

The exemplary immersion vessel 12 of FIGS. 1-9 is designed, inaccordance with one aspect of the present invention, to accommodate oneor more microelectronic device processing, such as for processing of aset of microelectronic devices 14. In FIG. 2 the major surface of onemicroelectronic device 29 of the set of microelectronic devices isillustrated. As illustrated, immersion vessel 12 can be generallyrectangularly shaped in cross-section for accommodating the set ofmicroelectronic devices 14, but may be any size and shape foraccommodating one or more microelectronic devices of any size and shape.For single device processing, vessel size can be reduced significantlyto reduce fluid usage. Preferably, for single device or any size set ofdevice processing, the vessel is sized and shaped to reduce or minimizeprocess fluid usage, balanced with the functional ability to providesufficient and effective process fluid flow to relevant device surfaces.

Specifically, the illustrated immersion vessel 12 comprises a pair ofspaced side walls 28, a pair of spaced end walls 30, and a bottom wall32. The side, end, and bottom walls 28, 30, and 32, respectively, andthe materials that make up all components within vessel 12 may compriseany material suitable for a particular processing liquid application,and may be formed of any number of separate components or as componentsintegral with one another. The side and end walls 28 and 30 arepreferably dimensioned to accommodate the height of a processing liquidrequired to cover the relevant portion of the one or moremicroelectronic devices 14 suspended or otherwise supported withinimmersion vessel 12. Further, the side and end walls 28 and 30 arepreferably formed to provide whatever fluid flow requirements are neededto permit sufficient processing liquid to flow with respect to the setof microelectronic devices 14. With other shaped vessels, the number,size and shape of the walls defining a containment vessel can varygreatly.

In accordance with an immersion process of the present invention, suchas a processing or rinsing step, it is preferable to flow processingliquid through the immersion vessel 12 past the set of microelectronicdevices 14. To controllably do this, a cascade rinser may be providedcomprising the immersion vessel 12 as an inner vessel along with anouter vessel 34 or other containment structure for collecting cascadedprocess fluid from the inner vessel. Alternatively, process fluid can besimply cascaded to whatever environment surrounds vessel 12, as may beappropriate depending on process fluid handling needs. An outer vessel34 or containment structure may completely surround immersion vessel 12or it may be provided only along one or more portions of the immersionvessel 12. In accordance with the illustrated embodiment, an outervessel 34 comprises outer side walls 36 that extend higher than topedges 38 of side walls 28 and which are operatively connected to outersurfaces of the side walls 28 by bottom wall 40 to create a weirstructure for controllably receiving process fluid from the inner vessel12. The outer side walls 36 may be operatively connected to the sidewalls 28 at or below the top edges 38 by any conventional or developedconnection or integral making technique. This design permits fluid flowover the top edges 38 and into channels 42 that are preferably createdbetween top portions of side walls 28 and the outer side walls 36. Theembodiment illustrated in FIGS. 1 through 9 also includes outer endwalls 44 (see FIG. 2) that along with top edges 46 of end walls 30connect with bottom wall 48 to define channels 50 as additional weirstructure.

In the illustrated embodiment of FIGS. 1 and 2, the top edges 38 ofsidewalls 28 and the top edges 46 of end walls 44 create a controllingpart of the weir structure over which processing liquid can flow. Suchtop edge surfaces may be flat, as shown, or may be tapered or angleddown or otherwise shaped into channels 42 and 50. One or more notches orother openings may also be provided to assist in fluid flow dynamicsand/or distribution along the weir structure. Where an immersion vessel12 doesn't include an outer vessel or weir structure, cascading flow canbe controlled in a similar manner by controlled flow over an edge, orflow can be effected by any fluid outlet or fluid flow control device ordevices in any arrangement.

For supplying processing liquid, one or more inlets, such as liquidinlet 52 permits fluid communication from a processing liquid source(not shown) into the interior of the immersion vessel 12. Such liquidinlet may be provided at the bottom (as shown) or anywhere along thesidewalls or from the top so long as process flow requirements are metbased upon any desired application. Preferably, the liquid inlet 52includes a valve 54 for controlling the flow of such liquid into theimmersion vessel 12. Processing liquid is supplied via the liquid inlet52 until the immersion vessel 12 is filled with processing liquidsuitable to cover the relevant microelectronic device surfaces fortreatment. As a cascade vessel, such as is illustrated in FIG. 8, liquidis supplied preferably completely up to its sidewall top edges 38 and46. As continued processing liquid is supplied, liquid will spill orcascade over the top edges 38 and 46 into the channels 42 and 50. Bottomwalls 40 and 48 of the outer vessel 34 help define the width of channels42 and 50, and also provide space to accommodate liquid drains 56 and 57formed in bottom walls 40 and 48 respectively of the outer vessel 34. Ifdesired, the channels 42 and 50 may each include an outer vessel liquiddrain 56, which drains themselves can be provided in any conventional ordeveloped way depending on the desired fluid flow characteristics. Thedrains 56 and 57 may also permit gas flow, such as from the nozzle 20and/or gas distribution devices 22, 24, and 26 to exit from theapparatus 10. Where other or no containment structure is provided,drains may be unnecessary.

After the set of microelectronic devices 14 is processed and/or rinsed,it is desirable in accordance with one aspect of the present inventionto remove or separate the one or more microelectronic devices 14 fromthe liquid environment and progressively introduce the set ofmicroelectronic devices 14 (or any portion thereof subjected to liquidbath or immersion treatment) to an environment containing gas.Separation thus can be characterized as the gradual replacement of theliquid environment surrounding the microelectronic devices 14 with a gasenvironment. Such a gas containing environment need not be completelygas, but it preferably is also extremely clean and contains only gasesthat will not adversely affect the set of microelectronic devices 14 orthat can enhance clean separation, as will be described below.

Draining of processing liquid from the immersion vessel 12 effectivelyseparates the set of microelectronic devices 14 from the processingliquid. The immersion vessel 12 is preferably drainable for removingprocessing liquid at any desired time by way of at least one immersionvessel drain 58, which preferably includes an adjustable flow valve 60for controlling the drain rate of the immersion vessel 12. Also, theimmersion vessel 12 may preferably include a quick dump drain 62,controllable by a valve 64 that may be used to provide fast removal ofprocessing liquid from the immersion vessel 12 when desired. That is, itmay be desirable to drain the processing liquid to a point below the setof microelectronic devices 14, such as to the floor support 15, at acontrolled rate by way of the drain 58 and then quickly remove theremaining processing liquid with the quick dump drain 62 accordingly.During drainage of the immersion vessel 12, the cascading effect (ifprovided for) would cease. It is noted that liquid inlet 52, drain 58,and quick dump drain 62 may be provided separately or combined togetheras desired by using any known or developed arrangement of plumbing,valves, fluid handling devices, or the like.

Preferably, the drain rate with respect to the microelectronic devicesurfaces is accurately controlled. For microelectronic devices, drainrate can be stated as a function of the rate that the gas environmentreplaces the liquid environment as experienced across a vertical surface(whether such a surface actually exists or not). For the purpose ofobtaining better separation, it is preferable that the gas environmentreplaces the liquid environment at a rate of around 5 mm per second orless. Preferably, the gas environment should replace the liquidenvironment at a rate of 2 mm per second or less. The rate ofreplacement can be controlled easily by controlling the flow of liquidfrom the immersion vessel 12, such as by utilizing a variable andcontrollable valve device as drain valve 60. Alternatively, the liquidenvironment can be removed by other conventional or developed liquidtransfer mechanisms utilizing gravity, positive pressure, siphons, orlike.

Preferably, the gas environment replaces the liquid environment at asubstantially constant rate while the replacement passes across themicroelectronic devices. However, it is contemplated that thereplacement rate can be varied if desired. Preferably also, after thereplacement passes the microelectronic devices, such as when the liquidlevel falls below the support structure 15, described above, the speedof drain can be increased, by either varying the opening of the drainvalve 60 and/or opening the dump valve 64. Preferably, the dump valve 64is fully opened to remove the remaining liquid quickly once the liquidlevel falls below the microelectronic devices.

Alternatively, the set of microelectronic devices 14 may be separatedfrom a processing liquid by a lifting type separation. That is, forcertain applications, the cassette 16 or other support device for one ormore microelectronic devices 14 can be raised from a processing liquidby a lifting mechanism or device such as a robot or the like. Such alift mechanism may comprise any known or developed system suitable forgripping the cassette 16 or microelectronic devices and moving them inand out of the interior space of the immersion vessel 12. To accommodatea lifting mechanism of any type, sufficient head space below lid 18would be provided within which the microelectronic devices could bepositioned, and such mechanism could be located within the head spacetoo or it could pass through such lid or other closure structure withappropriate accommodation.

It is also contemplated that microelectronic device separation could beconducted by any combination of lifting of microelectronic devices anddraining of processing liquid. Additionally, each of the inlet anddrains discussed above may be controlled by any conventional ordeveloped valve mechanisms and/or and further controlled by anyconventional or developed control systems for controlling fluid flowinto and out of the immersion vessel 12 and outer vessel 34 (or pluralportions thereof). With either a lift separation or combination of liftand drain separation, it is preferable, as above to control theseparation rate for enhanced separation of liquid from themicroelectronic surfaces.

In accordance with another aspect of the present invention, it ispreferable to introduce a cleaning enhancement substance into the gasenvironment for enhancing the process liquid flow from surfaces of themicroelectronic devices of the one or more microelectronic devices 14during a separation step as illustrated in FIG. 9. The cleaningenhancement substance provides for enhanced removal of liquid from thesurfaces of the microelectronic devices through a concentration gradientor mass transfer effect, e.g., Marongoni flow (described above in theBackground). This effect tends to increase or accelerate the flow ofliquid from surfaces of a microelectronic device. The use of knowncleaning enhancement substances carried in the gas environment affectsthe liquid meniscus on the microelectronic device surface as separationbetween the device surface and the liquid occurs to reduce surfacetension of the liquid attached to the microelectronic device surface,thereby increasing fluid flow therefrom. The cleaning enhancementsubstance is also believed to dope or mix within the liquid attached tothe microelectronic device surface, which mixing occurs in accordancewith a gradient of the concentration of the cleaning enhancementsubstance in the attached liquid to accelerate fluid flow of theattached liquid off of the microelectronic device surface. That is, thecleaning enhancement substance will be present at a higher concentrationwithin the liquid at the thinner upper region of each meniscus thatforms as a result of the separation process (the relative movement ofthe device surface with respect to the liquid tending to drag the liquidwith the surface) than at a lower region thereof, the effect of which isthe creation of the concentration gradient. The tendency for the dopedor higher concentration liquid with cleaning enhancement substance tomove toward liquid of lower concentration is the Marongoni effect, whicheffect is advantageous in removing liquid from microelectronic devicesurfaces. This fluid flow can also assist in pulling or drawing offparticles from microelectronic device surfaces.

Certain tensioactive compounds are known or may be developed foraffecting the surface tension between the microelectronic devicesurfaces and processing liquid at the interface of any microelectronicdevice surface, the processing liquid surface and the gas environment.Such tensioactive compounds can be provided easily within thereplacement gas environment either as gas or as liquid droplets atomizedor the like within the gas or may be delivered as liquid to the processliquid surface. A preferred example of such a tensioactive compound thatmay be delivered in gas or vapor form or as a liquid is isopropylalcohol (“IPA”). Other examples of suitable tensioactive compoundsinclude ethyleneglycol, 1-propanol, 2-propanol, tetrahydrofuran,1-butanol, diacetone alcohol, 2-ethoxy-ethanol, 1-methoxy-2-propanol,acetone, n-butyl acetate and hydrofluoroethers that have been morerecently developed. Tensioactive compounds may be delivered in manyphysical forms, and by many methods, e.g., in gas form, as a gas in acarrier gas, as a liquid, as an aerosol in a carrier gas or as anaerosol introduced directly into the process vessel. The cleaningenhancement substance is preferably delivered as a gas (with or withouta carrier gas). Methods for adding a cleaning enhancement substance to acarrier gas are described in commonly owned U.S. Pat. No. 5,772,784 toMohindra et al., the entire disclosure of which is incorporated hereinby reference.

A cleaning enhancement substance of the type described above can bedelivered to the immersion vessel 12 by a nozzle 20, one or more of thegas distribution devices 22, 24, and 26, or any combination thereof. Asshown in FIG. 3, nozzle 20 can be provided with one or more orifices 74in any desirable arrangement. Likewise, the illustrated gas distributiondevices 22, 24, and 26 include orifices 88, which are described indetail below. In one embodiment, a cleaning enhancement substance can besupplied from a cleaning enhancement substance source, discussed below,to the nozzle 20 by an inlet 68, can also include a controllable valve70, or the cleaning enhancement substance can be supplied to one or moreof the gas distribution devices 22, 24, and 26 by a supply inlet 110,which preferably includes a controllable valve 112. It is contemplatedthat each of the gas distribution devices 22, 24, and 26 may have anindividual gas supply or they may be commonly supplied by using anyknown or developed gas handling techniques or devices.

If used, the nozzle 20 can be operatively mounted to the lid 18, such asby mounting structures 66 as shown in FIGS. 1 and 2. As shown in FIG. 3,the nozzle 20 also may include plural rows 72 of the orifices 74 forcontrolled delivery of a cleaning enhancement substance to the immersionvessel 12. The nozzle 20 is preferably designed such that it is capableof substantially uniformly delivering cleaning enhancement substancewithin a gas environment as such replaces a liquid environment about themicroelectronic devices 14. As shown, the nozzle 20 is illustrated as aplate that extends in length and width to cover the set ofmicroelectronic devices 14. Although the nozzle 20 is illustrated as agenerally rectangular plate, the nozzle 20 may alternatively be formedas having any shape, such as a disk or showerhead or the like.Generally, it is preferred that the nozzle 20 is to cover at least aportion of the set of microelectronic devices 14 and preferably to coveran entire set. The nozzle 20 may comprise a single nozzle, asillustrated, or may comprise any number of distinct nozzles having oneor more delivery orifices for introducing cleaning enhancement substanceas described above.

Cleaning enhancement substance is preferably provided during the entireperiod over which the liquid environment is replaced by a gasenvironment with respect to the one or more microelectronic devicessupported within vessel 12. This replacement process being facilitatedby gas flow into the vessel 12 from any one or more of nozzle 20 and/orgas distribution devices 22, 24 and 26, as provided, and which gas flowcan be controlled based upon the desired gas pressure within vessel 12and as affected by the rate of removal of the liquid environment.

Depending on the specific application, however, it may be desirable tointroduce cleaning enhancement substance over less time than the fullreplacement step with respect to the relevant microelectronic devicesurfaces. Furthermore, it may be desirable to introduce such cleaningenhancement substance over a greater time period than the fullreplacement step. For example, it is preferable to continue to dispensecleaning enhancement substance beyond when the liquid level falls belowthe bottom of the microelectronic devices as supported within thevessel. As noted above and described in greater detail below, liquidsometimes accumulates at contact points between the support structure ofthe microelectronic devices within the vessel and the edges of themicroelectronic devices. By continuing cleaning enhancement substanceflow after the liquid level is below the microelectronic devices,accumulated or trapped liquid at such contact points tends to be bettercontained at those contact points. That is, drops that are formed atcontact points have less of the tendency to migrate from where there areformed. This is due to the tensioactive nature of the cleaningenhancement substance as it affects the contact angle of the liquidrelative to the device surface. As noted above, it is preferable toquickly drop the remaining liquid level via a quick dump during whichperiod, the cleaning enhancement substance is preferably still dispensedinto the gas environment. Then, as described below, a drying operationcan be commenced quickly after the liquid is gone (or even before) sothat any accumulated drops or liquid film portions can be more quicklydried with less opportunity to migrate to greater areas. If the contactpoints are effectively controlled at the microelectronic device edges,or the exclusion zone adjacent the edge, the continued cleaningenhancement substance flow can effectively help minimize potentialcontamination onto the usable surfaces of the microelectronic devices.It is contemplated that cleaning enhancement substance be delivered fora minute or longer to the gas environment within the vessel after theliquid level is below the microelectronic devices in order toeffectively contain potential liquid drops or films at such contactpoints. Such time may be shorter or even longer based upon specificoperation parameters and upon the operation of the drying step describedbelow, if conducted. It is preferable that the cleaning enhancementsubstance flow be continued even into the drying operation. It iscontemplated that such cleaning enhancement substance delivery can beeffected as an independent operation by providing cleaning enhancementsubstance (as gas or liquid) into the vessel 12 or as a combinedoperation with other gas delivery, such as carrier gas, replacement gas,or drying gas.

Another aspect of the present invention relative to the controlled flowof cleaning enhancement substance with the gas environment replacementof the liquid environment is to vary the flow or concentration ofcleaning enhancement substance into the gas environment. That is, flowrates or different gas concentrations of cleaning enhancement substancecan be varied according to select stages or continuously over periods orall of the separation process. When the immersion vessel 12 is drainedbecause the separation as described above at the desired rate ofreplacement, the flow rate of cleaning enhancement substance can beincreased, for example, as the liquid level becomes lower within thevessel 12. The flow of replacement gas in addition to the cleaningenhancement substance can also be controlled to accommodate adequate gasinput as part of the replacement process. Flow rates can be varied inaccordance with a stepped profile, a continuous or sloped profile, orcombinations thereof over the separation process or any portion thereof.Variances of flow rates can an increase, decrease, or mix thereof, andmay be done in conjunction with concentration variations of the cleaningenhancement substance. Variations of the cleaning enhancement substancemay also be done independently from flow rates.

According to one preferable process technique, gas and cleaningenhancement substance flow is minimized when the liquid level is highwithin the vessel 12 in order to minimize rippling of the liquid surfaceand any influence on surface flow of the liquid. As a level drops,however, flow rates may be increased at one or more times in order toensure sufficient delivery of cleaning enhancement substance to theliquid top surface and thus the menisci that are formed at surfaces ofthe microelectronic devices and to effectively replace the liquidenvironment with gas. The concentration of the cleaning enhancementsubstance over such flow changes can be the same or varied as well overtime. It is contemplated that the flow rates of the cleaning enhancementsubstance can be increased or decreased as stages or as a gradualcontinual process depending on a desired effect. It is preferable,however, to increase flow of cleaning enhancement substance into the gasenvironment as the liquid level lowers for adequate substance deliveryand effectiveness of the cleaning and rinsing operation. For potentialtime periods after the level falls below the microelectronic devices, itis contemplated that the cleaning enhancement substance flow rate can beincreased or decreased based upon a particular process and asempirically determined or otherwise predicted for the purposes discussedabove in containing droplets at contact points.

As part of the delivery process of the cleaning enhancement substance,FIG. 10 illustrates a provision of the cleaning enhancement substance ata desired concentration. Specifically, clean gas, such as ultrapurenitrogen (or any other preferably ultrapure, inert gas) is utilized topick up cleaning enhancement substance for delivery to the interior ofthe vessel 12. Alternatively, atomized liquid cleaning enhancementsubstance can be introduce directly into the vessel 12, or cleaningenhancement substance in liquid form can be dispensed onto the processliquid. Preferably, clean nitrogen gas is passed through a bubblervessel 200 containing a quantity of cleaning enhancement substance 202,such as IPA. The clean gas can be hot or cold and supplied at variousrates depending on the amount of cleaning enhancement substance to bepicked up by the gas flow.

Specifically, in FIG. 10, an exemplary system is illustrated including anitrogen supply 204 cleaning to a nitrogen heater 206 that is connectedby way of line 208 to a gas ring or sparger 210 with holes so thattemperature controlled nitrogen flows substantially from the bottom ofthe bubbler vessel 200 up through the volume of IPA 202. As result ofthis operation, IPA vapor is carried with the nitrogen gas flow throughfurther line 212 and preferably through a on/off type control valve 214for delivery to the interior of the immersion vessel 12, preferablythrough a further gas filter device 216. FIG. 10 also shows the nitrogensupply 204 connectable alternatively through the nitrogen heater 206with a delivery line 218 preferably connected by way of a variablycontrolled bypass valve 220 to the interior of vessel 12, againpreferably through gas filter 216. That way, clean nitrogen gas flow canbe delivered through the illustrated system through the bypass circuitincluding alternative delivery line 218 or through the bubbler vessel200 independently from one another as controlled by the control valve214 and bypass valve 220. It is contemplated that either manner may beutilized solely at any given time or that gas can be delivered throughboth subsystems together at controlled ratios in order to achievedesired gas flow rates and concentrations. Moreover, as described above,independent or combined gas and IPA delivery can be to any one or moreof nozzle 20 and devices 22, 24, and 26.

Another important aspect in affecting concentration of cleaningenhancement substance, in particular, is controlling how much cleaningenhancement substance vapor is or will be picked up by the nitrogen gasflow through the bubbler vessel 200. The nitrogen gas can be potentiallysaturated with IPA vapor through the bubbler vessel 200 based in partupon gas flow rates and the volume of IPA through which the nitrogen gasflows. It is also understood that temperature and pressure affect thepotential concentration of cleaning enhancement substance, like IPA,within a gas, such as nitrogen. Specifically, the temperature of thenitrogen/IPA mixture as it leaves the bubbler vessel 200 affects theamount of IPA that can be carried by the nitrogen gas. Likewise, thepressure of the nitrogen/IPA gas mixture, measured as back pressurewithin line 212 or head space gas pressure above the liquid IPA inbubbler vessel 200, affects such potential concentration of IPA in thenitrogen gas. Pressure and temperature of these points affect thepotential concentration of IPA within the nitrogen gas based upon knownprinciples and according to relationships that are commonly representedas curves charting temperature versus pressure as to the ability toachieve desired configurations of a desired vapor (for example) within adesired gas (e.g. a desired concentration of IPA in nitrogen at aspecific temperature and pressure). It is further understood that suchconcentration can be controlled by controlling temperature and pressure,as the outgoing concentration of IPA within nitrogen fits such knowncurves.

Heat can be supplied as part of the concentration system in any numberof ways including connective, conductive and/or radiant heat transfersystems. Similarly, if desired for any particular application, any typeof cooling system could be utilized. For example, heat could betransferred to or from the bubbler vessel 200 directly by any such heattransfer mechanism, which heat transfer would affect the temperature ofthe liquid IPA and thus the concentration of the nitrogen/IPA mixture.Alternatively, as illustrated in FIG. 10, the liquid IPA could be heated(or cooled) by heating (or cooling) the nitrogen gas, such as bynitrogen heater 206, which itself can controllably heat the gas by anyknown or developed technique. As such, heated nitrogen gas can add heatto the system for heating the liquid IPA and thus the more importantmixture of nitrogen and IPA as a concentration control. Temperature ofthe mixture, or any constituent part, can be monitored at any time onthe basis of a correspondence to the amount of heat to be supplied bygas heater 206 as part of a feedback control to achieve desire mixtureconcentration. For example, if the liquid IPA temperature is too cool,as monitored by a sensor 222, the nitrogen could be introduced at anelevated temperature.

Likewise, pressure of the mixture from the bubbler vessel 200 can bemonitored and controlled to achieve a desired mixture concentration ofcleaning enhancement substance in gas, such as IPA in nitrogen, takinginto account the machine temperature, constituent fluids and knownrelationships as represented by developed curves. Pressure within theheadspace of the bubbler vessel 200 is dependent upon the pressure ofintroduction of gas into the bubbler vessel 200 and the flow rate bywhich the mixture is allowed to escape. Such a flow rate is controllableby any type of flow controlling by valve or orifice, such as may bevariable to control a desired back pressures within line 212.Controlling back pressure in line 212 also controls the pressure withinthe headspace of bubbler vessel 200 and thus controllably affects theconcentration of IPA within the nitrogen/IPA mixture leaving the bubblervessel 200.

As an example for controlling back pressure effectively, a back pressureregulator 224 is illustrated in FIG. 10 that can be controlled toregulate the flow through the device based upon the monitoring of theback pressure upstream of the back pressure regulator 224. Suchregulators, per se, are conventionally known as may be driven to changeflow rates by a controller 226 that may be electric, mechanical,pneumatic or the like and based upon input information, such aselectrical signals, provided via an electrical connection 227 from apressure transducer 228 that is operative to sense pressure within thebubbler vessel 200, for example. Where such a back pressure regulator224 regulates the back pressure in line 212 upstream from itself, thevalve 214 is preferably a two position fully opened and closed typevalve.

Whatever level of saturation the nitrogen leaves the bubbler vessel 200,that concentration can, if desired, be further controlled or manipulatedby supply of additional nitrogen through line 218. In that case, thebypass valve 220 is preferably variable. Also, in any case, theconcentration of IPA is preferably controlled to be at or nearsaturation as it will be decreased substantially within the interior ofthe immersion vessel 12 once introduced into the gas environmentthereof, which environment at lower pressure can be provided solely bygas through a system such as that of FIG. 10 or supplemented with othergas supply.

According to preferred methods of utilizing cleaning enhancementsubstance as part of the separation and replacement process, cleaningenhancement substance is introduced during the entire period over whichthe liquid environment is replaced by the gas environment as suchreplacement passes across all microelectronic devices surfaces. Duringthis operation stage, it is preferable for processing 300 mm wafers orthe like to introduce the cleaning enhancement substance at asubstantially even concentration of between 0.5 percent and 3.6 percent,preferably between 1.5 percent and 2.0 percent. This concentration maychange significantly for microelectronic devices of different typesand/or sizes. However, for 300 mm wafers of the like, it is preferablethat the flow rate of the supply of nitrogen and IPA be increased instages starting at a flow rate of between 50 slm (standard liters perminute) and 200 slm and increasing by about between 50 slm and 100 slmat between 10 and 30 seconds time intervals while replacing the liquidenvironment with a gas environment at a rate of between 1 and 3 mm/sec.As above, these rates and times may be changed significantly formicroelectronic devices.

Then, it is further preferable to continue at about the final flow ratewhen the liquid level falls below the microelectronic devices while thelevel continues to be lowered at a controlled rate. After a short periodsufficient for the level to be sufficiently away from themicroelectronic devices to not potentially rewet them, the dump valve 64is preferably opened. A continued flow of cleaning enhancement substanceis still preferred, although potentially at a lower flow rate, or stagesof flow rates, through the quick dump and into a drying step, ifconducted, for containing liquid drops or films, such as at contactpoints, as discussed above.

It is also preferable to perform a step of drying after separating theset of microelectronic devices 14 from a processing liquid. The step ofdrying preferably substantially removes all liquid droplets adhering tocertain surfaces such as microelectronic device surfaces,microelectronic device edges, carrier edges, and the like, as well asany adsorbed liquid that may be present on a microelectronic devicesurface. As such, the principles of the present invention may be used todry microelectronic devices regardless of how such liquid dropletsand/or adsorbed liquid is introduced to the microelectronic devices.Liquid droplets and/or adsorbed liquid can be introduced tomicroelectronic devices by separation from a processing liquid, sprayingor rinsing, or from exposure to a humid environment, as examples.

Preferably, in accordance with the present invention, the gasdistribution devices 22, 24, and 26 are utilized to supply gas curtains76, 78, and 80, respectively, as shown in FIGS. 4 and 5 and described ingreater detail below. In FIG. 6 a perspective view of the gasdistribution device 24 is shown as an exemplary gas distribution devicein accordance with the present invention. It is noted that the gasdistribution devices 22 and 26 are preferably similar to the gasdistribution device 24 but need not be and may comprise any gasdistribution device such that the functional aspects of the presentinvention are achieved. Preferably, the gas distribution device 24 isformed as a tube-like structure, as illustrated, and includes a gasinlet at a first end 84, which gas inlet is preferably connectable to apressurized drying gas supply (not shown). A second end 86, opposite thefirst end 84, may also be connectable to a pressurized drying gas supply(not shown) or may be closed depending on the gas flow requirements. Thegas distribution devices 22, 24, and 26 may be formed from any suitablematerial.

Preferably, the gas distribution device 24 includes plural circularlyshaped orifices or openings 88 formed as a row of spaced apart orificesfor distributing gas therefrom. The orifices 88 may be any shape such ascircular, elliptical, square, rectangular, slot shaped, or the like.Preferably, the exemplary gas distribution device 24 of the presentinvention includes an arrangement of orifices 88 that can provide adirectional gas curtain such as the gas curtain 78 of FIGS. 4 and 5.Such a gas curtain can be provided by using a row of closely spacedorifices to provide a curtain-like stream of gas flow. That is,preferably each individual stream of gas flowing from each individualorifice contributes to the overall gas flow of the gas curtain. Theprovision of a gas curtain made up of individual directional gas streamscan be effected by using non-diverging orifices as orifices 88.Moreover, a sufficient number of closely spaced orifices 88 can enhancethe creation of a gas curtain. For example, one preferred arrangement oforifices 88 may be formed as a single row of orifices, each having adiameter of about 0.04 inches and spaced apart by about 0.2 inches for300 mm wafers with 5 mm pitch distance between wafers. Further, it iscontemplated that plural rows of any desired number of orifices 88 maybe used. If plural rows of orifices 88 are used, such rows may bepositioned such that orifices are adjacent to each other or the rows maybe arranged so that the orifices 88 are staggered or offset from eachother. The orifices 88 may include any designs for the purpose ofcontrolling the direction of gas flow from devices 22, 24 and 26 and mayinclude different designs within one device or from one device toanother.

Each of the gas distribution devices 22, 24, and 26 is preferablygenerally tube shaped, as shown. The gas distribution devices 22, 24,and 26 may, however, comprise any shape such that the gas curtains 76,78, and 80 can be controllably directed with respect to the set ofmicroelectronic devices 14 for providing adequate flow of drying gasaround the set of microelectronic devices 14 and/or for introduction ofother gas with or without cleaning enhancement substance. For example,the gas distribution devices 22, 24, and 26 may be square, rectangular,or plate shaped. Moreover, the gas distribution devices 22, 24, and 26may be provided as individual devices or may be formed as a singledevice capable of directionally providing any desired number of gascurtains such as the gas curtains 76, 78, and 80. Additionally, it isnoted that any number of gas distribution devices for providing anynumber of gas curtains may be used in order to achieve desired gas flowrequirements such as for different size microelectronic devices, forexample.

During a drying step, the gas curtains 76, 78, and 80 comprise at leastdrying gas. The drying gas can be any suitable gas capable of removingliquid from the microelectronic device edges, microelectronic devicesurfaces, and the like. The drying gas is preferably ultra-pure nitrogenand the like, but may also be a variety of other gases or gaseousmixtures that are preferably inert and ultraclean. In one preferredembodiment, the drying gas is heated ultra-pure nitrogen. Such dryinggas may preferably be heated so that it enters the chamber of vessel 12at a temperature of about between 50° C.-80° C. Preferably, the dryinggas is directed to the microelectronic devices at a temperature thateffectively vaporizes the process liquid more quickly than at roomtemperature.

Preferably, drying gas is supplied to the gas distribution devices 22,24, and 26 by the gas supply inlet 110, which preferably includes thevalve 112 for controlling the flow of gas. As mentioned above, each ofthe gas distribution devices 22, 24, and 26 may have a separate dryinggas supply or they may be commonly supplied by using any known ordeveloped gas handling techniques or devices.

In FIG. 7, the gas distribution device 24 is shown in partialcross-section positioned above microelectronic devices 90, 91, 92, and93. The microelectronic device 90 includes first and second majorsurfaces 94 and 95. Microelectronic device 91 includes first and secondmajor surfaces 96 and 97. Microelectronic device 92 includes first andsecond major surfaces 98 and 99. And, microelectronic device 93 includesfirst and second major surfaces 100 and 101.

The gas distribution device 24 preferably includes circularly shaped(see FIG. 7) orifices 102, 104, and 106 for supplying gas columns 112,114, and 116. As such, the gas columns may form a gas curtain inaccordance with the present invention such as the gas curtain 78.Preferably, the orifices 102, 104, and 106 comprise directional sidewalls 108 that are substantially non-diverging or non-converging forshaping columnar gas streams as illustrated. As such, the orifices 102,104, and 106 can each direct a columnar shaped stream of drying gas (aspart of the gas curtain 78) with respect to the major surfaces of themicroelectronic device being processed. As described above, theindividual columnar streams of gas from the orifices 102, 104, and 106collectively form the gas curtain. It is contemplated that such gasstreams could be diverging or otherwise, but it is preferable that thegas streams are substantially directional, as described below, at leastin a direction toward the microelectronic devices.

Preferably, the gas distribution device 24 is designed such that one ormore gas columns such as the gas columns 112, 114, and 116 can bedirected between pairs of microelectronic devices. Such is preferablyprovided for each microelectronic device supported within the vessel 12.In other words, a single gas column may be directed between each pair ofmicroelectronic devices or plural gas columns may be directed betweenany such pair of microelectronic devices. As shown, gas column 112 isdirected between microelectronic devices 90 and 91, gas column 114 isdirected between microelectronic devices 91 and 92, and gas column 116is directed between microelectronic devices 92 and 93. Although any gascolumn may be directed at a microelectronic device (not between), it ispreferred that at least one gas column is directed between pairs ofmicroelectronic devices. As such, a significant amount of substantiallyunobstructed gas flow over the surfaces of the microelectronic devicescan be provided. Such substantially unobstructed gas flow over themicroelectronic device surface results in improved microelectronicdevice drying characteristics with less microelectronic devicecontamination. It is noted that any number of gas distribution devicesmay be used for any number of microelectronic devices such as the gasdistribution devices 22, 24, and 26 described above.

The gas distribution devices 22, 24, and 26 preferably produce gas flowat a predetermined velocity to cover a desired number of microelectronicdevices. Each gas distribution device may produce gas flow of, forexample, nitrogen gas at any flow rate to generate any amount of dryinggas flow within the vessel; however, for 300 mm wafers, it is preferredfor each gas distribution device 22, 24 and 26 to deliver between 100slm and 300 slm, and more preferably about 200 slm. It is noted that thegas distributions devices 22 and 26 are preferably similar to the gasdistribution device 24 described above but may alternatively be designedto provide any desired flow characteristics, which flow characteristicmay be different from gas distribution device 24. Further, any number ofgas distribution devices may be used in accordance with the presentinvention, each of which may have different flow characteristics.

Preferably, the gas distribution devices 22, 24, and 26 are operativelyattached to the lid 18 so that each of the gas distribution devices 22,24, and 26 extends longitudinally in a direction generally perpendicularto a surface of a microelectronic device of the set of microelectronicdevices 14. That is, preferably, the gas distribution devices 22, 24,and 26 extend in a direction parallel to a central axis of an arrangedset of microelectronic devices 14 at predetermined spacing. Such anarrangement of the gas distribution devices 22, 24, and 26 can provide auniform gas flow regime with respect to the set of microelectronicdevices 14 within the immersion vessel 12 as is described below. It iscontemplated however, that the gas distribution devices 22, 24, and 26may be angularly oriented with respect to the surface of amicroelectronic device of the arranged set of microelectronic devices14, other than perpendicularly, to achieve any desired gas flowrequirements or uniformity depending on the application.

The gas distribution devices 22, 24, and 26 are preferably positioned tobe above and spaced apart from the set of microelectronic devices 14 asshown in FIGS. 1 and 2. Also, the illustrative gas distribution devices22, 24, and 26 are preferably equally spaced apart from each other,which spacing may be varied depending on the application. Spacingbetween devices 22, 24 and 26 and between orifices 88 thereof isdependent, in part, on the size of the microelectronic devicesprocessed, as well as on the pitch or spacing between them as such pitchis commonly set as a standard for particular sized devices or wafers asthey are to be supported for processing and transport. Like gas flowrates, spacings and sizes can be adjusted accordingly for improvedeffectiveness with different type and sizes of devices. Microelectronicdevices 14 are typically supported, as described above, by supportstructure within the vessel 12, by a movable cassette, or othertransport structure or the like. Moreover, such structure usuallydefines the spacing and arrangement of the microelectronic devices asthey will be processed. In accordance with the present invention, it isdesirable that the microelectronic devices 14 be supported within thevessel 12 according to a predetermined arrangement so that the gasdistribution device(s) 22, 24 and 26 utilized provide at least oneorifice 88 between each pair of microelectronic devices 14. Themicroelectronic devices 14 need not be regularly spaced or aligned at acommon central axis (in the case of circular wafers), but typically theywould be. In the gas of using linear extending gas distribution devices,such as 22, 24 and 26, it is preferable that the microelectronic devices14 at least be arranged generally linearly with general eveness ofspacing between any pair of microelectronic devices 14 for bettercontrolled gas flow between them.

The gas distribution devices 22, 24, and 26 may also be mounted to thelid so as to be equally spaced away from the lid 18 as illustrated. Assuch, the gas distribution devices 22, 24, and 26 can be removed withthe lid 18 so that the cassette 16 with the set of microelectronicdevices 14 may easily be moved into and out of the immersion vessel 12.Alternatively, the gas distribution devices 22, 24, and 26 may be spacedat differing distances from the set of microelectronic devices 14 orfrom each other depending on the application. The spacing of the gasdistribution devices 22, 24, and 26 from the set of microelectronicdevices 14 and from each other may be varied depending on the particularapplication. Factors considered in positioning the gas distributiondevices 22, 24, and 26 may include the microelectronic device size,processing fluid type, drying gas type, and desired flow characteristic.

In one illustrative embodiment shown in FIG. 4, the gas distributiondevices 22, 24, and 26 may be designed and provided to direct the gascurtains 76, 78, and 80 respectively in an initial direction generallyperpendicular to the bottom wall 32 of the immersion vessel 12 andparallel to the end walls 30. In other words, each of the gas curtains76, 78, and 80 are directed substantially perpendicularly to a referenceplane that passes through a central axis of the regularly arrangedmicroelectronic devices 14. In such an arrangement, it has beendiscovered that as the gas flow increases, the outer gas curtains 76 and80 may be drawn closer to the center gas curtain 78 by the flow of thegas curtain 78 as is illustrated in FIG. 4. Thus, for certainapplications, such as a process having high gas flow and largemicroelectronic devices, the gas curtains 76 and 80 may be drawn towardthe center gas curtain 78 away from the outside edges of themicroelectronic devices thereby reducing gas flow at the outside edgesof the microelectronic devices. Different gas flow rates from one gasdistribution device to another can be utilized to facilitate such.

It has further been discovered that the position of the gas curtains 76and 80 and the uniformity of the gas flow of the gas curtains 76, 78,and 80 together may be controllably adjusted. By directing the gascurtains 76 and 80 away from each other and toward the side walls 30, asillustrated in FIG. 5, gas flow over the microelectronic device surfacescan be controlled to provide a controlled gas flow and improved drying.That is, the gas curtains 76 and 80 are preferably directed at an angleaway from the gas curtain 78, whereas the combination affect with thedrawing tendency of the center gas curtain 78 is to controllably directthe drying gas flow. As illustrated in FIG. 5, it may be desirable tohave curtains 76 and 80 directed moreso to support contact points whereliquid has a greater tendency to accumulate. It is noted that thepositions of the gas distribution devices 22, 24, and 26, with respectto the set of microelectronic devices 14 and with respect to each other,as well as the angles of gas distribution devices 22 and 26 with respectto gas distribution device 24 may be empirically determined for aparticular application. In other words, a trial and error process may beused to characterize a particular immersion vessel 12 for achievingoptimized gas flow requirements for a particular microelectronic devicesize, for example. Note also that FIGS. 4 and 5 show certain desirableflow patterns through the devices and back within the immersion vessel,but that flow patterns back up the side walls and beyond are verydependent on design aspects of how the gas is exhausted and thus are notillustrated. Returning gas flow is also largely affected by spacingbetween the devices and side walls of the vessel, which spacing ispreferably minimized to reduce process chemical usage. Other factors mayalso affect such flow patterns, in particular after gas flows initiallypast the devices. For example, with some devices, it may be desirable toopen the quick dump valve or door which may further create back flowfrom ambient air.

As an example, when processing 300 mm microelectronic devices, three gasdistribution devices may preferably be used, such as the gasdistribution devices 22, 24, and 26 shown in FIG. 5. Preferably, the gasdistribution devices 22 and 26 are spaced apart by about 76 mm from eachother with the gas distribution device 24 approximately centered anequal distance between them. Also preferably, the set of microelectronicdevices 14 is positioned such that, as seen in cross-section in FIG. 5,the center of microelectronic device 29 is positioned about 185 mm fromthe center of the gas distribution device 24. More preferably, the gascurtain 78 is directed towards the bottom plate 32 while the gascurtains 76 and 80 are directed at an angle of about 30° away from thegas curtain 76 and toward the side walls 30.

Referring again to FIGS. 1 and 2, a preferred process in accordance withthe present invention may be performed as follows. A set ofmicroelectronic devices is preferably loaded into the cassette 16 by anytechnique such as by hand or by a robot. The immersion vessel 12 ispreferably filled with a rinsing liquid such as room temperature DIwater by liquid inlet 52 and allowed to cascade such that an overflowsensor or the like signals a robot, for example, to place the cassette16 into the immersion vessel 12 while the lid 18 is open. Alternatively,the cassette could be placed in the immersion vessel 12 before or anytime while DI water enters the immersion vessel 12. Once the cassette 16is positioned within the immersion vessel 12, the cascading DI water ispreferably allowed to cascade for a predetermined amount of time,depending upon the specific application. After such time period, theliquid inlet 52 is closed and drain 58 is opened, which allows the DIwater to drain from the immersion vessel 12 at a controlledpredetermined rate. At the same time that the drain is opened, any orall of the nozzle 20 and/or gas distribution devices 22, 24, and 26preferably introduce a cleaning enhancement substance and a carrier gassuch as nitrogen and IPA to the immersion vessel 12 at a rate sufficientto replace the draining liquid. Once the DI water is drained to apredetermined level, below the microelectronic devices for example, thequick dump drain 62 may be opened to rapidly remove the remaining DIwater. Once the DI water is substantially drained from the immersionvessel 12, drying gas, such as heated N2, is preferably delivered to theimmersion vessel by the gas distribution devices 22, 24, and 26 with orwithout delivery of cleaning enhancement substance. After apredetermined drying time, the drying gas is turned off, the lid 18 maybe opened, and the cassette 16 may be removed.

Numerous characteristics and advantages of the invention meant to bedescribed by this document have been set forth in the foregoingdescription. It is to be understood, however, that while particularforms or embodiments of the invention have been illustrated, variousmodifications, including modifications to shape, and arrangement ofparts, and the like, can be made without departing from the spirit andscope of the invention.

1. A method for processing at least one microelectronic devicecomprising: immersing at least a portion of at least one microelectronicdevice into a liquid bath provided within a vessel for performing atreatment on at least the immersed portion thereof; separating themicroelectronic device completely from the liquid bath by replacing saidliquid with a gas environment adjacent to the microelectronic device;and delivering a cleaning enhancement substance during said replacing,said cleaning enhancement substance causing a concentration gradient ofsaid cleaning enhancement substance in liquid at an interface betweenthe surface of the microelectronic device and the liquid bath to enhancefluid flow of from the microelectronic device surface, wherein thedelivery of the cleaning enhancement substance is continued after saidreplacing step is complete relative to the microelectronic device. 2.The method of claim 1, wherein the separation is performed by loweringthe liquid level within the vessel.
 3. The method of claim 2, whereinthe liquid level is lowered below the at least one microelectronicdevice and the delivery of cleaning enhancement substance is continuedwhile the liquid level is lowered further.
 4. The method of claim 3,wherein a quick dump of remaining liquid is conducted at a point afterthe liquid level is lowered below the at least one microelectronicdevice while cleaning enhancement substance is delivered.
 5. The methodof claim 4, further comprising a step of drying the at least onemicroelectronic device by supplying at least one gas stream directedwithin the vessel to dry a surface of the at least one microelectronicdevice, and wherein delivery of cleaning enhancement substance iscontinued for at least an initial portion of the drying step.
 6. Themethod of claim 1, wherein the delivery of the cleaning enhancementsubstance is varied during said replacing step.
 7. The method of claim6, wherein the delivery of cleaning enhancement substance is varied bychanging a flow rate of delivery of cleaning enhancement substance froma first flow rate to a second flow rate.
 8. The method of claim 7,wherein delivery of cleaning enhancement substance is further varied bychanging a flow rate of delivery of cleaning enhancement substance fromthe second flow rate to a third flow rate.
 9. The method of claim 8,wherein at least one flow rate is varied by increasing the flow rate.10. A method of drying a plurality of microelectronic devices, themethod comprising the steps of: supporting a plurality ofmicroelectronic devices in a drying environment such that themicroelectronic devices are provided in a substantially directionalarrangement at a predetermined spacing; and directing plural gas streamstoward the arranged microelectronic devices such that at least one gasstream is directed between adjacent microelectronic devices of thearranged plurality of microelectronic devices.
 11. The method of claim10 further including a step of separating the plurality ofmicroelectronic devices from a processing fluid wherein the plurality ofmicroelectronic devices are provided in a the same arrangement at apredetermined spacing.
 12. A method of drying a plurality ofmicroelectronic devices, the method comprising the steps of: supportinga plurality of microelectronic devices in a drying environment such thatthe microelectronic devices are provided in a substantially directionalarrangement at a predetermined spacing arranged; directing a first gascurtain toward the arrangement of microelectronic devices at a firstangle of incidence with respect to the arrangement of microelectronicdevices; directing a second gas curtain at an angle of incidence withrespect to the arrangement of microelectronic devices that is differentfrom the angle of incidence of the first gas curtain; and directing athird gas curtain at an angle of incidence with respect to thearrangement of microelectronic devices that is different from the angleof incidence of the first gas curtain.
 13. An immersion processingapparatus for processing a plurality of microelectronic devices, theapparatus comprising: a vessel for containing a liquid immersion bathand for receiving a plurality microelectronic devices to be positionedwithin the immersion vessel by support structure providing themicroelectronic devices in a substantially directional arrangement at apredetermined spacing; and a gas dispenser operatively positionedrelative to the vessel and connectable to a pressurized supply of dryinggas and for providing plural gas streams to a plurality of arrangedmicroelectronic devices when positioned within the vessel such that atleast one gas stream will be directed between adjacent microelectronicdevices of the plurality of arranged microelectronic devices.
 14. Theapparatus of claim 13, wherein the gas dispenser provides a gas curtainto a plurality of arranged microelectronic devices as they arepositionable within the vessel such that the gas curtain can be providedat a predetermined angle of incidence with respect to the arrangement ofthe microelectronic devices when positioned within the immersion vessel.15. The apparatus of claim 14, wherein the gas curtain comprises aplurality of gas streams.
 16. The apparatus of claim 15, wherein theplurality of gas streams are provided so that at least one gas stream isdirected between adjacent microelectronic devices of the plurality ofmicroelectronic devices.
 17. An apparatus for drying a plurality ofmicroelectronic devices, the apparatus comprising: a vessel forcontaining a liquid immersion bath; a support means for positioningmicroelectronic devices in a substantially directional arrangement at apredetermined spacing within the immersion vessel; a first gas dispenseroperatively positioned with respect to the support device andconnectable to a pressurized supply of drying gas and for directing afirst gas curtain at a first angle of incidence with respect to thearrangement of the microelectronic devices when positioned on thesupport means; a second gas dispenser operatively positioned adjacent toand spaced from the first gas dispenser and connectable to a pressurizedsupply of drying gas and for directing a second gas curtain at a secondangle of incidence with respect to the arrangement of microelectronicdevices that is different from the first angle of incidence of the firstgas curtain; and a third gas dispenser operatively positioned adjacentto and spaced from the first gas dispenser and opposite the second gasdispenser and connectable to a pressurized supply of drying gas and fordirecting a third gas curtain at a third angle of incidence with respectto the reference plane that is different from the first angle ofincidence of the first gas curtain.
 18. The apparatus of claim 17,wherein the first gas dispenser is located centrally of both the secondand third gas dispensers.